Graphene Printing

What they are trying to accomplish here is the outright synthesis of graphene as a working layer directly onto an active substrate.  We sure could not print it on, but this is indicative that there will emerge a method to do the equivalent.

With that in place, mass production of graphene based chips can begin immediately.

I continue to be impressed by the speed with which graphene is emerging as a working technology.  I still am looking for continuous ribbon production with a seamed edge to use as cabling.  We can first test that out on cable stayed bridges operating at the limits of concrete compressive strength.  Then we can figure out how to rig a space elevator.

EMPA Identifies Reaction Pathway To Fabricate Graphene-Like Materials

by Staff Writers
Zurich, Switzerland (SPX) Nov 22, 2010

Graphene is a promising material for tomorrow's nanoelectronics devices. Precise and upscaleable methods to fabricate graphene and derived materials with desired electronic properties are however still searched after.

To overcome the current limitations, Empa researchers have fabricated graphene-like materials using a surface chemical route and clarified in detail the corresponding reaction pathway. The work has just been published in the scientific journal "Nature Chemistry". The scientists combined empirical observations using scanning tunnelling microscopy with computer simulations.

Electronic components are getting smaller and smaller, with microelectronic components gradually being replaced by nanoelectronic ones. On nanoscale dimensions, silicon, which is at the present stage the most commonly used material in semiconductor technology, reaches however a limit, preventing further miniaturization and technological progress.

New electronic materials are therefore in great demand. Due to its outstanding electronic properties, graphene, a two-dimensional carbon network, is considered as a possible replacement.

However, several obstacles must be overcome before graphene can be used in semiconductor technology. For instance, currently there is no easily applicable method for large-scale processing of graphene-like materials.

Empa researchers of the nanotech@surfaces Laboratory reported on a surface chemical route to fabricate small fragments of graphene, so-called nanographenes. Using a prototypical polyphenylene precursor, the researchers clarified, together with scientists at the Max Planck Institute for Polymer Research in Mainz (Germany) and the University of Zurich, how the reaction pathway runs in detail on a copper surface und how the building blocks can be transformed into planar nanographenes directly on the surface.

The work has been published in the scientific journal "Nature Chemistry" as an advanced online publication.

Successful partners: experiment and simulation

For their investigations the researchers combined empirical observations, in particular from scanning tunnelling microscopy with computer simulations. The simulations are used to determine whether a theoretically possible reaction step is energetically possible or not.

The result: the reaction pathway consists of six steps with five intermediate products. Two of them are stabilised by the surface so that they can be stably imaged with the scanning tunnelling microscope. The reaction barriers connecting the different intermediates are lowered through a catalytic effect of the substrate.

To be capable of being integrated in electronic circuits, the graphene-like material must however be manufactured on semiconductor surfaces instead of metal ones. The researchers have simulated whether their approach could also work on these surfaces and the results are very promising, showing that surface-supported synthesis is a possible way to fabricate tailored nanographenes on a range of different substrates.

The three pillars of today's science: theory, experiment, and simulation

Progress in today's scientific research relies at the same time on theory, experiments, and to an increasing extent on computer simulations.

These simulations are complementary to often complex lab experiments and make it possible to get further information that cannot be obtained with experimental methods alone.

The combination of experiments and simulations as well as the deduced theories therefore allow for a more and more accurate explanation and precise prediction of natural phenomena.

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