This is a lot more on graphene’s rise to prominence. It is quickly been folded into manufacturing protocols. Note the text I underlined showing how to pull apart graphite into clean pieces of graphene suitable for application work.
This shows us a cost effective route to mass production.
I suspect we will see it in everything in a couple of years because it allows a leap ahead in general efficiency. We are really seeing the end of the silicon age.
Korea Makes Graphene 25 Inch Touchscreen and RPI a New Technique Enables Large-Scale Production of Graphene at Room Temperature
JUNE 21, 2010
Researchers have created a flexible graphene sheet with silver electrodes printed on it (top) that can be used as a touch screen when connected to control software on a computer (bottom). Credit: Byung Hee Hong, SKKU. 2. Researchers at Samsung and Sungkyunkwan University, in Korea, have produced a continuous layer of pure graphene the size of a large television, spooling it out through rollers on top of a flexible, see-through, 63-centimeter-wide (25 inch) polyester sheet.
The team has already created a flexible touch screen by using the polymer-supported graphene to make the screen's transparent electrodes. The material currently used to make transparent electronics, indium tin oxide, is expensive and brittle. Producing graphene on polyester sheets that bend is the first step to making transparent electronics that are stronger, cheaper, and more flexible. "You could theoretically roll up your iPhone and stick it behind your ear like a pencil," says Tour
2. Researchers at Rensselaer Polytechnic Institute have developed a simple new method for producing large quantities of the promising nanomaterial graphene. The new technique works at room temperature, needs little processing, and paves the way for cost-effective mass production of graphene.
By submerging graphite in a mixture of dilute organic acid, alcohol, and water, and then exposing it to ultrasonic sound, the team discovered that the acid works as a “molecular wedge, ” which separates sheets of graphene from the parent graphite. The process results in the creation of large quantities of undamaged, high-quality graphene dispersed in water. Kar and team then used the graphene to build chemical sensors and ultracapacitors
We present a scalable and facile technique for noncovalent functionalization of graphene with 1-pyrenecarboxylic acid that exfoliates single-, few-, and multilayered graphene flakes into stable aqueous dispersions. The exfoliation mechanism is established using stringent control experiments and detailed characterization steps. Using the exfoliated graphene, we demonstrate highly sensitive and selective conductometric sensors (whose resistance rapidly changes >10000% in saturated ethanol vapor), and ultracapacitors with extremely high specific capacitance (120 F/g), power density (105 kW/kg), and energy density (9.2 Wh/kg).
Researchers at Rensselaer Polytechnic Institute Develop New Method for Mass-Producing Graphene
New, Simple Technique Enables Large-Scale Production of Graphene at Room Temperature; Researchers Use Graphene to Build Chemical Sensors, Ultracapacitors
Graphene, as seen in the above renderings, is an atom-thick sheet of carbon arranged in a honeycomb structure. It has unique mechanical and electrical properties and is considered a potential heir to copper and silicon as the fundamental building blocks of nanoelectronics, but is difficult to produce in bulk. A team of Rensselaer researchers has brought science a step closer to realizing this important goal of a simple, efficient way to mass-produce graphene. Image Credit: Rensselaer/Kar
A scanning electron microscope image of the nanomaterial graphene made with a new technique from researchers at Rensselaer . The new, room-temperature method needs little processing and paves the way for cost-effective mass production of graphene. Photo Credit: Rensselaer/Kar
Researchers at Rensselaer Polytechnic Institute have developed a simple new method for producing large quantities of the promising nanomaterial graphene. The new technique works at room temperature, needs little processing, and paves the way for cost-effective mass production of graphene.
An atom-thick sheet of carbon arranged in a honeycomb structure, graphene has unique mechanical and electrical properties and is considered a potential heir to copper and silicon as the fundamental building block of nanoelectronics. Since graphene’s discovery in 2004, researchers have been searching for an easy method to produce it in bulk quantities.
A team of interdisciplinary researchers, led by Swastik Kar, research assistant professor in the Department of Physics, Applied Physics, and Astronomy at Rensselaer, has brought science a step closer to realizing this important goal. By submerging graphite in a mixture of dilute organic acid, alcohol, and water, and then exposing it to ultrasonic sound, the team discovered that the acid works as a “molecular wedge, ” which separates sheets of graphene from the parent graphite. The process results in the creation of large quantities of undamaged, high-quality graphene dispersed in water. Kar and team then used the graphene to build chemical sensors and ultracapacitors.
“There are other known techniques for fabricating graphene, but our process is advantageous for mass production as it is low cost, performed at room temperature, devoid of any harsh chemicals, and thus is friendly to a number of technologies where temperature and environmental limitations exist,” Kar said. “The process does not need any controlled environment chambers, which enhances its simplicity without compromising its scalability. This simplicity enabled us to directly demonstrate high-performance applications related to environmental sensing and energy storage, which have become issues of global importance.”
Results of the study, titled “Stable Aqueous Dispersions of Non-Covalently Functionalized Graphene from Graphite and their Multifunctional High-Performance Applications,” were published online Thursday, June 17, 2010, by the journalNano Letters. The study will also be the cover story of the November print edition of Nano Letters.
Graphene eluded scientists for years but was finally made in the laboratory in 2004 with the help of a common office supply – clear adhesive tape. Graphite, the common material used in most pencils, is made up of countless layers of graphene. Researchers at first simply used the gentle stickiness of tape to pull layers of graphene from a piece of graphite.
Today, graphene fabrication is much more sophisticated. The most commonly used method, however, which involves oxidizing graphite and reducing the oxide at a later stage in the process, results in a degradation of graphene’s attractive conductive properties, Kar said. His team took a different route.
The researchers dissolved 1-pyrenecarboxylic acid (PCA) in a solution of water and methanol, and then introduced bulk graphite powder. The pyrene part of PCA is mostly hydrophobic, and clings to the surface of the also-hydrophobic graphite. The mixture is exposed to ultrasonic sound, which vibrates and agitates the graphite. As the molecular bonds holding together the graphene sheets in graphite start to weaken because of the agitation, the PCA also exploits these weakening bonds and works its way between the layers of graphene that make up the graphite. Ultimately, this coordinated attack results in layers of graphene flaking off of the graphite and into the water. The PCA also helps ensure the graphene does not clump and remains evenly dispersed in the water. Water is benign, and is an ideal vehicle through which graphene can be introduced into new applications and areas of research, Kar said.
“We believe that our method also will be useful for applications of graphene which require an aqueous medium, such as biomolecular experiments with living cells, or investigations involving glucose or protein interactions with graphene,” he said.
Using ultrathin membranes fabricated from graphene, the research team developed chemical sensors that can easily identify ethanol from within a mixture of different gases and vapors. Such a sensor could possibly be used as an industrial leakage detector or a breath-alcohol analyzer. The researchers also used the graphene to build an ultra-thin energy-storage device. The double-layer capacitor demonstrated high specific capacitance, power, and energy density, and performed far superior to similar devices fabricated in the past using graphene. Both devices show great promise for further performance enhancements, Kar said.
Co-authors on the Nano Letters paper are Rensselaer Post Doctoral Research Associate Xiaohong An; Assistant Professor Kim M. Lewis; Clinical Professor and Center for Integrated Electronics Associate Director Morris Washington; and Professor Saroj Nayak, all of the Department of Physics, Applied Physics, and Astronomy; Rensselaer post-doctoral researcher Trevor Simmons of the Department of Chemistry and Chemical Biology; along with Rakesh Shah, Christopher Wolfe, and Saikat Talapatra of the Department of Physics at Southern Illinois University Carbondale.
The research project was supported by the Interconnect Focus Center New York at Rensselaer, as well as the National Science Foundation (NSF) Division of Electrical, Communications and Cyber Systems.
For more information on Kar’s research, visit his website at:
For more information on graphene research at Rensselaer , visit:
- Graphene Outperforms Carbon Nanotubes for Creating Stronger, More Crack-Resistant Materials
- http://news.rpi.edu/update.do?artcenterkey=2715
- Student Inventor Tackles Challenge of Hydrogen Storage –
- http://news.rpi.edu/update.do?artcenterkey=2690
- Light-Speed Nanotech: Controlling the Nature of Graphene –
- http://news.rpi.edu/update.do?artcenterkey=2528
- Graphene Nanoelectronics: Making Tomorrow’s Computers from a Pencil Trace
- - http://news.rpi.edu/update.do?artcenterkey=2253
Published June 21, 2010
Contact: Michael Mullaney
Phone: (518) 276-6161
E-mail: mullam@rpi.edu
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